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For an electrochemical reaction to occur, the reacting species usually needs to adsorb to the electrode surface before undergoing reduction or oxidation, after which the resulting product species desorbs back into the electrolyte. If the rate of adsorption or desorption is slow in ... 詳細を見る

This example applies the Electrophoretic Transport and Laminar Flow interfaces to model isoelectric separation in a free-flow electrophoresis device. A stream containing six different ionic species is shown to be divided into pure component streams by means of migrative transport in an ... 詳細を見る

This model incorporates the transport and electrolytic reaction in the treatment of tumor tissue. Oxygen evolution at the anode produces protons, which lowers the pH, while chlorine production also leads to lowered pH through the hydrolysis of chlorine. One effect of a low pH is the ... 詳細を見る

A bipolar membrane consists of one anion-selective, and one cation-selective membrane, in contact with each other. The combined cation and anion selectivity makes the bipolar membrane highly impermeable to all ions, with the exception of H+ and OH- which are formed by water splitting ... 詳細を見る

Zone electrophoresis (ZE) is an electrophoretic separation technique typically used for analyzing proteins, nucleic acids, and biopolymers. During the process, different species in a sample are transported in a continuous electrolyte buffer system, subject to a potential gradient. Due to ... 詳細を見る

The common electroanalytical method of exhaustive amperometric detection in a microscopic thin layer is modelled as a 1D-symmetric diffusion problem. The simulated result agrees with the analytical Cottrell equation at short times, and deviates as expected at long times when the ... 詳細を見る

The purpose of this model is to visualize the electric potential in an electrochemical cell, for example a battery. This is done at OCV and during operation. In a battery, this would correspond to OCV, discharge, and recharge. The potential profile is explained both for cells with planar ... 詳細を見る

This example models the desalination of water by capacitive deionization in a "flow-between" cell (fbCDI). The model geometry is in 2D. Steady Brinkman flow, a tertiary current distribution, and the improved modified Donnan description of the deionization process is assumed. 詳細を見る

This model file was used for creating the plots featured in the blog post "How to Model Ion-Exchange Membranes and Donnan Potentials". 詳細を見る

This asset contains the model file described in the blog post titled "Approaching an Electrochemical Model from Scratch: Lemon Battery". 詳細を見る