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Due to its high capacity, silicon (Si) is often added to graphite in the negative electrode of lithium-ion batteries. Silicon–graphite blended electrodes may exhibit significant thermodynamic voltage hysteresis (“path dependence”) because the equilibrium potential of the lithium–silicon ... 詳細を見る
In the diffuse double layer and within the first few nanometers of an electrode surface, the assumption of electroneutrality is not valid due to charge separation. Typically, the diffuse double layer may be of interest when modeling very thin layers of electrolyte including those in ... 詳細を見る
This example applies the Electrophoretic Transport and Laminar Flow interfaces to model isoelectric separation in a free-flow electrophoresis device. A stream containing six different ionic species is shown to be divided into pure component streams by means of migrative transport in an ... 詳細を見る
The electrochemical cell shown in this model can be regarded as a unit cell of a larger wire-mesh electrode that is common in many industrial processes. One of the most important aspects in the design of electrochemical cells is the current density distributions in the electrolyte and ... 詳細を見る
Some positive electrode materials are known to deteriorate in overcharged lithium-ion battery cells. Predominantly, manganese containing electrode materials such as LMO and NMC can loose capacity due to manganese dissolving from the materials at overcharge. This decomposition is a ... 詳細を見る
Electrochemical supercapacitors feature relatively higher energy densities than conventional capacitors. With several advantages, such as fast charging, long charge–discharge cycles, and broad operating temperature ranges, electrochemical supercapacitors have found wide applications in ... 詳細を見る
This tutorial demonstrates how to use stationary polarization data to perform parameter estimation of a polymer electrolyte membrane fuel cell (PEMFC) model. The model, defining a 5-layer membrane electrode assembly (MEA) is two-dimensional and includes electronic and ionic charge ... 詳細を見る
